RAS Chemistry & Material ScienceНеорганические материалы Inorganic Materials

  • ISSN (Print) 0002-337X
  • ISSN (Online) 3034-5588

Preparation and Properties of Glasses in the Tellurium Dioxide–Sodium Hexametaphosphate System

PII
10.31857/S0002337X2302015X-1
DOI
10.31857/S0002337X2302015X
Publication type
Status
Published
Authors
Volume/ Edition
Volume 59 / Issue number 2
Pages
185-190
Abstract
New glasses in the TeO2–Na6P6O18 system have been prepared, their thermal behavior has been studied by differential scanning calorimetry in the range 25–580°C, and their heat capacity has been determined as a function of temperature in the range 25–400°C. We have evaluated characteristics of the devitrification process and glassy state, obtained analytical representations of the glass transition temperature and the thermodynamic characteristics of the glasses as functions of their composition at 80°C, and carried out a comparative analysis of the results together with those for previously studied TeO2-based binary systems. Optical transmission of the glasses has been measured in the UV, visible, and IR spectral regions. We have demonstrated the possibility of doping the glasses with rare-earth oxides and studied luminescence properties of the glass with the composition 0.89TeO2–0.08Na6P6O18–0.03Nd2O3.
Keywords
стекло диоксид теллура гексаметафосфат натрия стеклование теплоемкость калориметрия спектр пропускания люминесценция
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
4

References

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