RAS Chemistry & Material ScienceНеорганические материалы Inorganic Materials

  • ISSN (Print) 0002-337X
  • ISSN (Online) 3034-5588

Raising the Efficiency of Antimony(III) Ion Extraction from Solutions by Modified Titanium(IV) Oxyhydroxyphosphate-Based Sorbents

PII
10.31857/S0002337X23080134-1
DOI
10.31857/S0002337X23080134
Publication type
Status
Published
Authors
Volume/ Edition
Volume 59 / Issue number 8
Pages
847-852
Abstract
We have proposed compositions of titanyl hydrogen phosphate-based sorption materials modified with zirconium(IV) cations and containing both cation and anion exchange functional centers, represented by НРО and OH– groups, respectively. The synthesized materials were tested in sorption of antimony(III) cations and anions from high-salt solutions. Increasing the concentration of functional groups in ion exchange matrices has been shown to increase their affinity for antimony(III) ions. Such compositions can be regarded as promising ion exchange materials for efficient extraction of antimony radionuclides from multicomponent high-salt liquid radioactive waste.
Keywords
жидкие радиоактивные отходы радионуклиды сурьмы сорбенты модифицирование цирконий(IV) оксогидроксофосфаты титана(IV)
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
3

References

  1. 1. Takahatake Y., Watanabe S., Shibata A., Nomura K., Koma Y. Decontamination of Radioactive Liquid Waste with Hexacyanoferrate(II) // Procedia Chem. 2012. № 7. P. 610–615.
  2. 2. Abdel-Karima A.M., Zaki A.A., Elwana W., El-Naggar M.R., Gouda M.M. Experimental and Modeling Investigations of Cesium and Strontium Adsorption onto Clay of Radioactive Waste Disposal // Appl. Clay Sci. 2016. № 132–133. P. 391–401. https://doi.org/10.1016/j.clay.2016.07.005
  3. 3. Mansy M.S., Hassana R.S., Selim Y.T., Kenawy S.H. Evaluation of Synthetic Aluminum Silicate Modified by Magnesia for the Removal of 137Cs, 60Co and 152+154Eu from Low-Level Radioactive Waste // Appl. Radiat. Isot. 2017. № 130. P. 198–205. https://doi.org/10.1016/j.apradiso.2017.09.042
  4. 4. Kong T.Y., Kim S., Lee Y., Son J.K., Maeng S.J. Radioactive Effluents Released from Korean Nuclear Power Plants and the Resulting Radiation Doses to Members of the Public // Nucl. Eng. Technol. 2017. № 49. P. 1772–1777. https://doi.org/10.1016/j.net.2017.07.021
  5. 5. Nishad P.A., Bhaskarapillai A., Velmurugan S. Nano-Titania-Crosslinked Chitosan Composite as a Superior Sorbent for Antimony (III) and (V) // Carbohydr. Polym. 2014. № 108. P. 169–175. https://doi.org/10.1016/j.carbpol.2014.02.091
  6. 6. Gil-Díaz T., Schäfer J., Pougnet F., Abdou M., Dutruch L., Eyrolle-Boyer F., Coynel A., Blanc G. Distribution and Geochemical Behaviour of Antimony in the Gironde Estuary: A First Qualitative Approach to Regional Nuclear Accident Scenarios // Mar. Chem. 2016. № 185. P. 65–73. https://doi.org/10.1016/j.marchem.2016.02.002
  7. 7. Remya Devi P.S., Joshi S., Verma R., Lali A.M., Gantayet L.M. Effect of Gamma Radiation on Organic Ion Exchangers // Radiat. Phys. Chem. 2010. № 79. P. 41–45.https://doi.org/10.1016/j.radphyschem.2009.08.002
  8. 8. Roberts C.J. Management and Disposal of Waste from Sites Contaminated by Radioactivity // Radiat. Phys. Chem. 1998. V. 51. № 4–6. P. 579–587.
  9. 9. Korneikov R.I., Ivanenko V.I. Extraction of Cesium and Strontium Cations from Solutions by Titanium(IV) Phosphate-Based Ion Exchangers // Inorg. Mater. 2020. V. 56. № 5. P. 502–506. https://doi.org/10.1134/S0020168520050088
  10. 10. Милютин В.В., Некрасова Н.А., Козлитин Е.А. Селективные неорганические сорбенты в современной прикладной радиохимии // Матер. II Всерос. науч. конф. с международным участием “Исследования и разработки в области химии и технологии функциональных материалов” Спецвыпуск отделения “Химия и материаловедение”. Апатиты: Изд-во КНЦ РАН, 2015. С. 418–421.
  11. 11. Korneikov R.I., Ivanenko V.I., Petrov A.M. Extraction of Antimony(III) Ions from Solutions by Sorbents Based on Titanium(IV) Compounds // Inorg. Mater. 2021. V. 57. № 5. P. 524–528. https://doi.org/10.1134/S0020168521050046
  12. 12. Рябчиков Б.Е. Очистка жидких радиоактивных отходов. М.: ДеЛи принт, 2008. 516 с.
  13. 13. Ivanenko V.I., Lokshin E.P., Korneikov R.I., Kalinnikov V.T. Increase in the Performance of Titanium Phosphate Sorbents by Modifying with Transition Metal Cations // Doklady Chemistry. 2011. V. 439. № 2. P. 230–232. https://doi.org/10.1134/S0012500811080039
  14. 14. Korneikov R.I., Aksenova S.V., Ivanenko V.I., Lokshin E.P. Stability of Titanyl Hydrogen Phosphates in Aqueous Media // Inorg. Mater. 2018. V. 54. № 7. P. 689–693. https://doi.org/10.1134/S0020168518070063
  15. 15. Ivanenko V.I., Korneikov R.I., Lokshin E.P. Immobilization of Metal Cations with Titanium PhosphatE Sorbents // Radiochemistry. 2016. V. 58. № 2. P. 159–166. https://doi.org/10.1134/S1066362216020089
QR
Translate

Индексирование

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library